sarain A
27 March 2006
8,804 views
2 Comments

Overman, Garg & Hiebert. ACIE, 2006, EarlyView. DOI: 10.1002/anie.200600417
Rather strange looking beast; two fused macrocycles in a pentacyclic system. The final cyclisation goes via a Stille coupling, using the trans- vinyl stannane and a cis- vinyl iodide. However, more interesting to me was the condensation approach for creation of the eight-member ring in 86%. Nice.












Good accomplishment but waaaay to long…
mp3 guru…
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